Jewelry

Sunday, May 19, 2013

Emerald

Emerald is a gemstone, and a variety of the mineral beryl (Be3Al2(SiO3)6) colored green by trace amounts of chromium and sometimes vanadium.[2] Beryl has a hardness of 7.5–8 on the 10-point Mohs scale of mineral hardness.[2] Most emeralds are highly included, so their toughness (resistance to breakage) is classified as generally poor.

The word "Emerald" is derived (via Old French: Esmeraude and Middle English: Emeraude), from Vulgar Latin: Esmaralda/Esmaraldus, a variant of Latin Smaragdus, which originated in Greek: σμάραγδος (smaragdos; "green gem").

Emeralds, like all colored gemstones, are graded using four basic parameters–the four Cs of Connoisseurship: Color, Cut, Clarity and Crystal. The last C, crystal, is simply a synonym for transparency, or what gemologists call diaphaneity. Before the 20th century, jewelers used the term water, as in "a gem of the finest water,"[3] to express the combination of two qualities: color and crystal. Normally, in the grading of colored gemstones, color is by far the most important criterion. However, in the grading of emeralds, crystal is considered a close second. Both are necessary conditions. A fine emerald must possess not only a pure verdant green hue as described below, but also a high degree of transparency to be considered a top gem.[4]
In the 1960s, the American jewelry industry changed the definition of 'emerald' to include the green vanadium-bearing beryl as emerald. As a result, vanadium emeralds purchased as emeralds in the United States are not recognized as such in the UK and Europe. In America, the distinction between traditional emeralds and the new vanadium kind is often reflected in the use of terms such as 'Colombian Emerald.'[5]

Color

Scientifically speaking, color is divided into three components: hue, saturation and tone. Emeralds occur in hues ranging from yellow-green to blue-green, with the primary hue necessarily being green. Yellow and blue are the normal secondary hues found in emeralds. Only gems that are medium to dark in tone are considered emerald; light-toned gems are known instead by the species name green beryl. The finest emerald are approximately 75% tone on a scale where 0% tone would be colorless and 100% would be opaque black. In addition, a fine stone should be well saturated; the hue of an emerald should be bright (vivid). Gray is the normal saturation modifier or mask found in emerald; a grayish-green hue is a dull green hue.[4]
Emeralds are green by definition (the name is derived from the Greek word 'smaragdus', meaning green).[6] Emeralds are the green variety of beryl, a mineral which comes in many other colors that are sometimes also used as gems, such as blue aquamarine, yellow heliodor, pink morganite and colorless goshenite.[7]

Clarity

Emerald tends to have numerous inclusions and surface breaking fissures. Unlike diamond, where the loupe standard, i.e. 10X magnification, is used to grade clarity, emerald is graded by eye. Thus, if an emerald has no visible inclusions to the eye (assuming normal visual acuity) it is considered flawless. Stones that lack surface breaking fissures are extremely rare and therefore almost all emeralds are treated, "oiled", to enhance the apparent clarity. Eye-clean stones of a vivid primary green hue (as described above) with no more than 15% of any secondary hue or combination (either blue or yellow) of a medium-dark tone command the highest prices.[4] This relative crystal non-uniformity makes emeralds more likely than other gemstones to be cut into cabochons, rather than faceted shapes.

Treatments

Most emeralds are oiled as part of the post-lapidary process, in order to improve their clarity. Cedar oil, having a similar refractive index, is often used in this generally accepted practice. Other liquids, including synthetic oils and polymers with refractive indexes close to that of emerald such as Opticon are also used. The U.S. Federal Trade Commission requires the disclosure of this treatment when a treated emerald is sold.[8] The use of oil is traditional and largely accepted by the gem trade. Other treatments, for example the use of green-tinted oil, are not acceptable in the trade. The laboratory community has recently standardized the language for grading the clarity of emeralds. Gems are graded on a four step scale; none, minor, moderate and highly enhanced. Note that these categories reflect levels of enhancement, not clarity. A gem graded none on the enhancement scale may still exhibit visible inclusions. Laboratories tend to apply these criteria differently. Some gem labs consider the mere presence of oil or polymers to constitute enhancement. Others may ignore traces of oil if the presence of the material does not materially improve the look of the gemstone.
Given that the vast majority of all emeralds are treated as described above, and the fact that two stones that appear visually similar may actually be quite far apart in treatment level and therefore in value, a consumer considering a purchase of an expensive emerald is well advised to insist upon a treatment report from a reputable gemological laboratory. All other factors being equal, a high quality emerald with moderate enhancement should cost half the price of an identical stone graded none.

Emerald localities

Spanish emerald and gold pendant exhibited at Victoria  Albert Museum.
Emeralds in antiquity[when?] were mined in Egypt, India, and Austria. Colombia is by far the world's largest producer of emeralds, constituting 50–95% of the world production, with the number depending on the year, source and grade.[10][11][12][13] Emerald production in Colombia has increased drastically in the last decade, increasing by 78% from 2000 to 2010.[14] The three main emerald mining areas in Colombia are Muzo, Coscuez, and Chivor.[15] Rare 'trapiche' emeralds are found in Colombia, distinguished by a six-pointed radial pattern made of ray-like spokes of dark carbon impurities.

Zambia is the world's second biggest producer, with its Kafubu River area deposits (Kagem Mines) about 45 km southwest of Kitwe responsible for 20% of the world's production of gem quality stones in 2004.[16] In the first half of 2011 the Kagem mines produced 3.74 tons of emeralds.[17] Zambian emeralds are of very high quality, being less porous and brittle than Colombian emeralds, with more even color.
Emeralds are found all over the world in countries such as Afghanistan, Australia, Austria, Brazil,[18] Bulgaria, Cambodia, Canada, China, Egypt, Ethiopia, France, Germany, India, Italy, Kazakhstan, Madagascar, Mozambique, Namibia, Nigeria, Norway, Pakistan, Russia, Somalia, South Africa, Spain, Switzerland, Tanzania, United States, Zambia, and Zimbabwe.[1] In the US, emeralds have been found in Connecticut, Montana, Nevada, North Carolina, and South Carolina.[1] In 1997 emeralds were discovered in the Yukon.[19]








Monday, May 13, 2013

Diamond Exhibition



The NJ/NY Gem and Jewelry show. The first show was attended by 6,000 visitors and had 115 exhibitors offering minerals, fossils, meteorites, gems, jewelry, gold, silver, opals, petrified wood, and much more. Both the general public and advanced collectors were wowed by the specimens in the 'Fine Mineral and Gem Gallery'. And the $2 million worth of genuine dinosaurs skeletons was not to be missed! We also debuted the 4-ton 'American Woman' sculpture chiseled from a single 21-ton block of Colorado marble. The enthusiastic response from our visitors set the course for a much bigger and better show the following year in 2013. But first we had to move to a larger venue, which was the 150,000 square foot NJ Conference and Exposition Center. For a 2012 show report click the 'Read More' button.

NYC Metro Show 2012 033It doesn't get much better than this! A lovely sky blue topaz crystal from Itinga, Jequitinhonha Valley, Minas Gerais, Brazil, occupies center position and entices the eye. Or how about that exquisite Meikle Mine barite, from the Bootstrap District, Elko County, Nevada. I'm running out of adjectives here! Not too shabby - the tall statuesque green tourmaline with lepidolite from Itinga is probably the exact, extreme opposite of shabby! 


 
NYC Metro Show 2012 034Almost Unbelievable. This giant sized, partially etched heliodore from Minas Gerais, Brazil seemed like it was about 10 inches tall at least, and probably weighed about 10 lbs. or more.







NYC Metro Show 2012 039A "rockin" gold in quartz from the colorful and historical 16 to 1 Mine, in Sierra County, California. The gold production from this long running mine was once estimated at one million ounces. That's a staggering value considering today's spot price. I'm not sure I can hold all those zeros in my brain!







NYC Metro Show 2012 037The "Africa Nugget" is a continent shaped gold that was found near Bendigo, Victoria, Australia. As the tag indicates this awesome nugget was displayed at the American Museum of Natural History's GOLD! exhibit, in 2008.






NYC Metro Show 2012 035Practically Peerless. This textbook, gem aquamarine crystal from the Shigar Valley, Northern Areas of Pakistan, rises up to a foot in height.









NYC Metro Show 2012 036Exploding Wave! This quartz, var. amethyst, from Guerrero, Mexico, has a great look, with nice dark, gemmy, undamaged crystals. It stands probably at least 10 inches tall.






NYC Metro Show 2012 041This superb botryoidal chalcedony mass from the Withlacoochie River of Lowndes County Georgia is the finest example of a chalcedony from that area ever found. What can I say? I'm an Oregon guy. I brake for agates!





NYC Metro Show 2012 062Bigger than a basketball. Maybe even two basketballs! This huge aquamarine and muscovite cluster was displayed by Arif and Aisha Jan, of Rocksaholics. It was found in Nagar, Hunza Valley, Northern Areas of Pakistan. The sweet natured and unpretentious couple had a very fine display of Pakistani minerals. The aquamarines from this area have to be some of the finest in the world.



NYC Metro Show 2012 064Another superb large aquamarine and muscovite cluster from Rock saholics. I guess you can tell these were my favorites.







NYC Metro Show 2012 063A juicy watermelon tourmaline perches on a huge smoky quartz elestial, in this fine specimen from Paprock, Nuristan Province, Afghanistan.....continue reading







Saturday, May 4, 2013

History of Diamond

In mineralogy, diamond (from the ancient Greek αδάμας – adámas "unbreakable") is a metastable allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions. Diamond is renowned as a material with superlative physical qualities, most of which originate from the strong covalent bonding between its atoms. In particular, diamond has the highest hardness and thermal conductivity of any bulk material. Those properties determine the major industrial application of diamond in cutting and polishing tools and the scientific applications in diamond knives and diamond anvil cells.

Diamond has remarkable optical characteristics. Because of its extremely rigid lattice, it can be contaminated by very few types of impurities, such as boron and nitrogen. Combined with wide transparency, this results in the clear, colorless appearance of most natural diamonds. Small amounts of defects or impurities (about one per million of lattice atoms) color diamond blue (boron), yellow (nitrogen), brown (lattice defects), green (radiation exposure), purple, pink, orange or red. Diamond also has relatively high optical dispersion (ability to disperse light of different colors), which results in its characteristic luster. Excellent optical and mechanical properties, notably unparalleled hardness and durability, make diamond the most popular gemstone.
Most natural diamonds are formed at high temperature and pressure at depths of 140 to 190 kilometers (87 to 120 mi) in the Earth's mantle. Carbon-containing minerals provide the carbon source, and the growth occurs over periods from 1 billion to 3.3 billion years (25% to 75% of the age of the Earth). Diamonds are brought close to the Earth′s surface through deep volcanic eruptions by a magma, which cools into igneous rocks known as kimberlites and lamproites. Diamonds can also be produced synthetically in a high-pressure high-temperature process which approximately simulates the conditions in the Earth mantle. An alternative, and completely different growth technique is chemical vapor deposition (CVD). Several non-diamond materials, which include cubic zirconia and silicon carbide and are often called diamond simulants, resemble diamond in appearance and many properties. Special gemological techniques have been developed to distinguish natural and synthetic diamonds and diamond simulants.

The name diamond is derived from the ancient Greek αδάμας (adámas), "proper", "unalterable", "unbreakable", "untamed", from ἀ- (a-), "un-" + δαμάω (damáō), "I overpower", "I tame".[3] Diamonds are thought to have been first recognized and mined in India, where significant alluvial deposits of the stone could be found many centuries ago along the rivers Penner, Krishna and Godavari. Diamonds have been known in India for at least 3,000 years but most likely 6,000 years.[4]
Diamonds have been treasured as gemstones since their use as religious icons in ancient India. Their usage in engraving tools also dates to early human history.[5][6] The popularity of diamonds has risen since the 19th century because of increased supply, improved cutting and polishing techniques, growth in the world economy, and innovative and successful advertising campaigns.[7]
In 1772, Antoine Lavoisier used a lens to concentrate the rays of the sun on a diamond in an atmosphere of oxygen, and showed that the only product of the combustion was carbon dioxide, proving that diamond is composed of carbon. Later in 1797, Smithson Tennant repeated and expanded that experiment. By demonstrating that burning diamond and graphite releases the same amount of gas he established the chemical equivalence of these substances.

The most familiar use of diamonds today is as gemstones used for adornment, a use which dates back into antiquity. The dispersion of white light into spectral colors is the primary gemological characteristic of gem diamonds. In the 20th century, experts in gemology have developed methods of grading diamonds and other gemstones based on the characteristics most important to their value as a gem. Four characteristics, known informally as the four Cs, are now commonly used as the basic descriptors of diamonds: these are carat, cut, color, and clarity. A large, flawless diamond is known as a paragon.

Natural history

The formation of natural diamond requires very specific conditions—exposure of carbon-bearing materials to high pressure, ranging approximately between 45 and 60 kilobars (4.5 and 6 GPa), but at a comparatively low temperature range between approximately 900 and 1,300 °C (1,652 and 2,372 °F). These conditions are met in two places on Earth; in the lithospheric mantle below relatively stable continental plates, and at the site of a meteorite strike.[10]

Formation in cratons

One face of an uncut octahedral diamond, showing trigons (of positive and negative relief) formed by natural chemical etching
A triangular facet of a crystal having triangular etch pits with the largest having a base length of about 0.2 millimetres (0.0079 in)The conditions for diamond formation to happen in the lithospheric mantle occur at considerable depth corresponding to the requirements of temperature and pressure. These depths are estimated between 140 and 190 kilometers (87 and 120 mi) though occasionally diamonds have crystallized at depths about 300 kilometers (190 mi).[11] The rate at which temperature changes with increasing depth into the Earth varies greatly in different parts of the Earth. In particular, under oceanic plates the temperature rises more quickly with depth, beyond the range required for diamond formation at the depth required. The correct combination of temperature and pressure is only found in the thick, ancient, and stable parts of continental plates where regions of lithosphere known as cratons exist. Long residence in the cratonic lithosphere allows diamond crystals to grow larger. 

Through studies of carbon isotope ratios (similar to the methodology used in carbon dating, except with the stable isotopes C-12 and C-13), it has been shown that the carbon found in diamonds comes from both inorganic and organic sources. Some diamonds, known as harzburgitic, are formed from inorganic carbon originally found deep in the Earth's mantle. In contrast, eclogitic diamonds contain organic carbon from organic detritus that has been pushed down from the surface of the Earth's crust through subduction (see plate tectonics) before transforming into diamond. These two different source of carbon have measurably different 13C:12C ratios. Diamonds that have come to the Earth's surface are generally quite old, ranging from under 1 billion to 3.3 billion years old. This is 22% to 73% of the age of the Earth. 

Diamonds occur most often as euhedral or rounded octahedra and twinned octahedra known as macles. As diamond's crystal structure has a cubic arrangement of the atoms, they have many facets that belong to a cube, octahedron, rhombicosidodecahedron, tetrakis hexahedron or disdyakis dodecahedron. The crystals can have rounded off and unexpressive edges and can be elongated. Sometimes they are found grown together or form double "twinned" crystals at the surfaces of the octahedron. These different shapes and habits of some diamonds result from differing external circumstances. Diamonds (especially those with rounded crystal faces) are commonly found coated in nyf, an opaque gum-like skin. 

Space diamonds

Primitive interstellar meteorites were found to contain carbon possibly in the form of diamond (Lewis et al. 1987).[13] Not all diamonds found on Earth originated here. A type of diamond called carbonado that is found in South America and Africa may have been deposited there via an asteroid impact (not formed from the impact) about 3 billion years ago. These diamonds may have formed in the intrastellar environment, but as of 2008, there was no scientific consensus on how carbonado diamonds originated.[14][15]
Diamonds can also form under other naturally occurring high-pressure conditions. Very small diamonds of micrometer and nanometer sizes, known as microdiamonds or nanodiamonds respectively, have been found in meteorite impact craters. Such impact events create shock zones of high pressure and temperature suitable for diamond formation. Impact-type microdiamonds can be used as an indicator of ancient impact craters.[10] Popigai crater in Russia may have the world's largest diamond deposit, estimated at trillions of carats, and formed by an asteroid impact.[16]
Scientific evidence indicates that white dwarf stars have a core of crystallized carbon and oxygen nuclei. The largest of these found in the universe so far, BPM 37093, is located 50 light-years (4.7×1014 km) away in the constellation Centaurus. A news release from the Harvard-Smithsonian Center for Astrophysics described the 2,500-mile (4,000 km)-wide stellar core as a diamond.[17] It was referred to as Lucy, after the Beatles' song "Lucy in the Sky With Diamonds".[18][19]

Transport from mantle

Schematic cross section of an underground region 3 km deep and 2 km wide. A red dike stretches across the bottom, and a pipe containing some xenoliths runs from the dike to the surface, varying from red at the bottom to orange-yellow at the top. The pipe's root, at its bottom, is about 1 km long, and its diatreme, above the root, is about 1.5 km long. The pipe's top is a crater, rimmed by a tuff ring and containing washed-back ejecta. The erosion level is almost zero for Orapa, about 1 km for Jagersfontein, and about 1.4 km for Kimberley.
Schematic diagram of a volcanic pipe

Diamond-bearing rock is carried from the mantle to the Earth's surface by deep-origin volcanic eruptions. The magma for such a volcano must originate at a depth where diamonds can be formed—150 km (93 mi) or more (three times or more the depth of source magma for most volcanoes). This is a relatively rare occurrence. These typically small surface volcanic craters extend downward in formations known as volcanic pipes. The pipes contain material that was transported toward the surface by volcanic action, but was not ejected before the volcanic activity ceased. During eruption these pipes are open to the surface, resulting in open circulation; many xenoliths of surface rock and even wood and fossils are found in volcanic pipes. Diamond-bearing volcanic pipes are closely related to the oldest, coolest regions of continental crust (cratons). This is because cratons are very thick, and their lithospheric mantle extends to great enough depth that diamonds are stable. Not all pipes contain diamonds, and even fewer contain enough diamonds to make mining economically viable.[11]

The magma in volcanic pipes is usually one of two characteristic types, which cool into igneous rock known as either kimberlite or lamproite.[11] The magma itself does not contain diamond; instead, it acts as an elevator that carries deep-formed rocks (xenoliths), minerals (xenocrysts), and fluids upward. These rocks are characteristically rich in magnesium-bearing olivine, pyroxene, and amphibole minerals[11] which are often altered to serpentine by heat and fluids during and after eruption. Certain indicator minerals typically occur within diamantiferous kimberlites and are used as mineralogical tracers by prospectors, who follow the indicator trail back to the volcanic pipe which may contain diamonds. These minerals are rich in chromium (Cr) or titanium (Ti), elements which impart bright colors to the minerals. The most common indicator minerals are chromium garnets (usually bright red chromium-pyrope, and occasionally green ugrandite-series garnets), eclogitic garnets, orange titanium-pyrope, red high-chromium spinels, dark chromite, bright green chromium-diopside, glassy green olivine, black picroilmenite, and magnetite. Kimberlite deposits are known as blue ground for the deeper serpentinized part of the deposits, or as yellow ground for the near surface smectite clay and carbonate weathered and oxidized portion.

Once diamonds have been transported to the surface by magma in a volcanic pipe, they may erode out and be distributed over a large area. A volcanic pipe containing diamonds is known as a primary source of diamonds. Secondary sources of diamonds include all areas where a significant number of diamonds have been eroded out of their kimberlite or lamproite matrix, and accumulated because of water or wind action. These include alluvial deposits and deposits along existing and ancient shorelines, where loose diamonds tend to accumulate because of their size and density. Diamonds have also rarely been found in deposits left behind by glaciers (notably in Wisconsin and Indiana); in contrast to alluvial deposits, glacial deposits are minor and are therefore not viable commercial sources of diamond....continue reading...